Studies on coordination compounds—VIII. Syntheses, structural, magnetic, spectral and thermal properties of some cobalt(II), nickel(II) and copper(II) complexes of 2-aminopyrimidine
Identifieur interne : 001105 ( Main/Exploration ); précédent : 001104; suivant : 001106Studies on coordination compounds—VIII. Syntheses, structural, magnetic, spectral and thermal properties of some cobalt(II), nickel(II) and copper(II) complexes of 2-aminopyrimidine
Auteurs : Paavo O. Lumme [Finlande] ; Hilkka Knuuttila [Finlande]Source :
- Polyhedron [ 0277-5387 ] ; 1995.
Abstract
The complexes bis[triaqua(2-aminopyrimidine)-μ-sulphato-O,O′-cobalt(II)] dihydrate (1), catena-[diaqua(2(2-aminopyrimidine))-μ-sulphato-O,O′nickel(II)]2-amino-pyrimidine (2), [pentaaqua(2-aminopyrimidine)nickel(II)]sulphate 2-aminopyrimidine (3) and catena-[aqua(2(2-aminopyrimidine))-μ-sulphato-O,O′-copper(II)] dihydrate (4) were prepared, structure determined by X-ray methods and physical properties studied by magnetic, IR, NMR, EPR and reflectance methods. The thermal behaviour was studied by TG and mass spectrometric methods. The results are discussed on a structural basis.
Url:
DOI: 10.1016/0277-5387(94)00442-H
Affiliations:
- Finlande
- Finlande-Centrale, Uusimaa
- Helsinki, Jyväskylä
- Université d'Helsinki, Université de Jyväskylä
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